Anomalous Charge Transfer from Organic Ligands to Metal Halides in Zero-Dimensional [(C6H5)4P]2SbCl5 Enabled by Pressure-Induced Lone Pair-π Interaction

Hui Luo, Kejun Bu, Yanfeng Yin, Dong Wang, Cuimi Shi, Songhao Guo, Tonghuan Fu, Jiayuan Liang, Bingyan Liu, Dongzhou Zhang, Liang-Jin Xu, Qingyang Hu, Yang Ding, Shengye Jin, Wenge Yang, Biwu Ma, Xujie Lü, “Anomalous Charge Transfer from Organic Ligands to Metal Halides in Zero-Dimensional [(C[subscript 6]H[subscript 5])[subscript 4]P][subscript 2]SbCl[subscript 5] Enabled by Pressure-Induced Lone Pair-[pi] Interaction,” Angew. Chem. Int. Ed. 62 (17), e202304494 (2023). DOI: 10.1002/anie.202304494